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Lithium-Ion Battery Electrolytes Stabilizer Triphenyl Phosphite

Triphenyl Phosphite Metal Surface To Form A Pale Yellow Dense Film Which Has Good Corrosion Resistance, High Temperature, Impact Resistance Can Be Used As A Crude Oil Distillation Unit And Pipeline Corrosion Inhibitor. Using Triphenyl Phosphite As A Naphthenic Acid Corrosion Inhibitor Research System Has Not Been Reported. In This Paper, SEM And IR Studies Triphenyl Phosphite Nature And Structure Of The Film On The Surface Of Steel A3 In.


Film Forming Properties Of Triphenyl PhosphiteTriphenyl Phosphite Is An Excellent Polydentate Ligand, Which Can Be Of Three Oxygen Atoms And Iron Ion Coordinated A3 Steel Surface To Form Complexes. Firmly Adsorbed On The Metal Surface To Form A Pale Yellow Dense Film Time. In Order To Determine The Nature Of Triphenyl Phosphite A3 Steel Surface Forming A Film By SEM Surface Film Was Observed. FIG. 1 Is At 200 ℃, The Concentration Of 500mg / L, Triphenyl Phosphite Surface Into Steel A3 Microscopic Morphology Of The Film To See From Figure 1: Crystal Uniform Particle Size, Dense Membrane At 8000 Times Under Complete Observation, Also Found No Further Observation Holes Can Be Seen: The Crystal Particle Packing Tightly Stacked Grain Direction, To The Plane And Spatial Development, The Membrane Has A Three-Dimensional Structure. FIG Estimate Grain Size Is Determined By The Diameter Of About 2μM.


Film And The Metal Substrate Triphenyl Phosphite Metal Surface To Form A Combination Of Tight, We Need To Go Through The Water Mill Sandpaper To Remove The Membrane, Showing A Good Abrasion And Impact Resistance. This Performance Suitable For Use In High Velocity Lines The Lithium-Ion Battery Electrolytes Stabilizer Triphenyl Phosphite, In Order To Determine The Nature Of The Ligand Triphenyl Phosphite And Iron Ions, Infrared Reflectance Spectroscopy The Composition Of The Film, The Results Shown In Figure 2. Figure 2a Is A Tris Phenyl Ester Standard Full Spectrum Of The Relevant νC-H And νC-OP Detailed Map, Resulting In A CH Vibration 3000cm-1 And The Appearance Of The Absorption Peak Chu 1000cm-1, 2000cm-1 Peak CH Chu As Octave Vibration, 1600cm-1 And 1500cm-1 Absorption Peak Of C = C Vibration, 730cm-1 Absorption Peak Is A Benzene Ring Monosubstituted (CH Characteristic Peaks, 1200cm-1 To Be In A Position Of Characteristic Absorption Peaks νC-OP. FIG. 2b Is A Film-Forming Surface Reflectance Infrared Spectra Of The Samples Can Be Seen That There Has Been Caused By The CH Vibration Absorption Lines Of 2926.42cm-1 And 519.33cm-1 In Wave Number. Correspond POC Spectral Lines Appear In 1134.49cm-1 Wave Number, And The Standard Spectrum Characterized Wavenumber 1200cm-1 As Compared To, νC-OP Figure 2b Vibration Frequency To The Low Frequency Mobile Units Description:. COP Bond Length Becomes Long Table Minya Triphenyl Phosphate And Iron Occurred To Further Confirm The Role Of Iron Ions And Asia. Triphenyl Phosphate To Form Coordination Compounds. Using Ethanol As Solvent, In Equal Moles Of Ferrous Chloride And Triphenyl Phosphite Mixing Can Be Observed Weak Absorption Peaks (FIG. 2C) In 1165.21cm-1, With 1:2 Molar Ratio Mixture (Figure 2d Is), The Absorption Peak At 1165.21cm-1 Has Been Enhanced To 1:3 Mixed In A Molar Ratio Of Infrared Absorption Peak Near 1200cm-1 Significantly Enhanced (FIG. 2e Of), The Reaction IR Spectrum (1165.21) And The Resulting Triphenyl Phosphite Produced (1134.49cm-1) Close 1134.49cm-1 Can Be Further Identified By The Following Absorption Peak Produced By Coordination Bond:. POC Mask Table Is Determined As A Result : Coordination Compounds Of Iron And Triphenyl Phosphite Formed Because Iron Ion Coordination Number Is Usually 6 To Form Octahedral Complexes More Stable Test Results Can Be Integrated 1,2 Speculate Triphenyl Phosphite And Iron. Ion Ligands May Have Single-Core And Dual-Core Two Structures Shown In Figure 3. Taking Into Oxygen Atoms Triphenyl Phosphite Ligands Of Forceps Shorter Ligand Complexes Octahedron (A) It Will Be Possible To Energy A More Favorable Configuration Of A Triangular Prism Distortion (B). In Fe Mononuclear Coordination Complexes, A And B Are Two Kinds Of Isomers May Coexist. Both Coordination Complexes To Which Based Or Coexist For Further Study, Naphthenic Acid In Reaction To [1]: Fe + 2RCOOH → Fe (RCOO) 2 + H2 And Carboxyl Vibration Peaks At νC-O At 1416cm-1 At The Fig. 3b, In 1460.36cm-1 May Mean That The Carboxyl Absorption Accordingly Its Ligand Reaction:. Fe (RCOO) 2 + 3 (C3H5O) 3P- [Fe [C3H5O] 3P] 3 (RCOO) 2 With About Consisting Of Compounds Need To Be Further Study. Lithium-Ion Battery Electrolytes Stabilizer Triphenyl Phosphite

Triphenyl Phosphite Reacts With The Iron In The Steel Surface To Form A Precipitate Film A3 Compact Molecular Structure Of The Nuclear Structure Of Coordination Compounds May Be Formed By A Single-Core And Dual-Core Two Structures.

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